METHYL GLYOXAL

Synonyms. Methyl glyoxal; 1-Ketopropionaldehyde; 2-Ketopropionaldehyde; 2-Oxopropanal; 2-Oxopropionaldehyde; Acetalformaldehyde; Acetylformaldehyde; Acetylformyl; alpha-Ketopropionaldehyde; alpha-Ketopropionic aldehyde; Methylglyoxal; Propanedione; Propanolone; Pyroracemic aldehyde; Pyruvaldehyde; Pyruvic aldehyde;

METHYL GLYOXAL

Click for original image

 

PRODUCT IDENTIFICATION

CAS RN

78-98-8

EINECS RN

201-164-8

FORMULA

CH3COCHO

MOLE WEIGHT

72.06

H.S CODE

2914.40.4000

SMILES

C(=O)(C=O)C

CLASSIFICATION

Aldehyde

EXTRA NOTES

An organic compound used often as a reagent in organic synthesis, as a flavoring agent, and in tanning. It has been demonstrated as an intermediate in the metabolism of acetone and its derivatives in isolated cell preparations, in various culture media, and in vivo in certain animals. [MeSH]
FEMA No. 2969
Overall Carcinogenic Evaluation: Group 3

 

PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE.

 

MELTING POINT

-20 C

BOILING POINT

72 C

DENSITY

1.17

SOLUBILITY IN WATER

 

SOLVENT SOLUBILITY

 

VAPOR DENSITY

 

log P(octanol-water)

-1.5

VAPOR PRESSURE

26.7 mm Hg

AUTOIGNITION TEMP

 
pK

 

REFRACTIVE INDEX

1.4209

FLASH POINT

> 72 C

 

STABILITY AND REACTIVITY
STABILITY Stable under normal conditions.

INCOMPATIBLE MATERIALS

Strong oxidizing agents, bases, amines, inorganic acids.

POLYMERIZATION

Has not been reported

NFPA RATINGS

Health: 2, Flammability: 2, Reactivity: 0

 

EXTERNAL LINKS & GENERAL DESCRIPTION

USA.gov - Methyl glyoxal

Wikipedia Linking - Methylglyoxal

Google Scholar Search - Methyl glyoxal

U.S. National Library of Medicine - Methyl glyoxal

PubChem Compound Summary - Pyruvoyl Group

Drug Bank -  Methylglyoxal

KEGG (Kyoto Encyclopedia of Genes and Genomes) -  Methyl glyoxal

http://www.ebi.ac.uk/chebi/ -  Methyl glyoxal

http://www.ncbi.nlm.nih.gov/ -  Methyl glyoxal

Material Safety Data Sheet - Methyl glyoxal

Hazardous Substances Data Bank - Methyl glyoxal

EPA - Substance Registry Services - Methyl glyoxal

 

SALES SPECIFICATION

APPEARANCE

clear to yellow solution

ASSAY

38 ~ 42%

pH

1 ~ 3

WATER

Balance

FREE ACID

7.0% max

 

TRANSPORT & REGULATORY INFORMATION

UN NO.

3265

HAZARD CLASS

8

PACKING GROUP III

 

SAFETY INFORMATION

HAZARD OVERVIEW

GHS (Globally Harmonised System) Classification: Acute toxicity (Oral). Eye irritation. Hazard statements: Harmful if swallowed. Causes serious eye damage. Suspected of causing genetic defects. Potential Health Effects: Eye - May cause eye burns. Risk of serious damage to eyes. Skin - Causes skin irritation. May cause skin burns. May be harmful if absorbed through the skin. Ingestion - May cause burns to the digestive tract. May be harmful if swallowed. Inhalation - Causes respiratory tract irritation. May cause burns to the respiratory tract. May be harmful if inhaled.

SIGNAL WORD Danger

PICTOGRAMS

PICTOGRAM_GHS08_health.jpgPICTOGRAM_GHS05_corrosion.jpg

HAZARD STATEMENTS

H303-H318-H341

P STATEMENTS

P305 + P351 + P338

EC DIRECTIVES

 

HAZARD CODES

CODE_Xn_Xi_harmful_Irritant.gif

RISK PHRASES

41-68

SAFETY PHRASES

26

 

PACKING

Preserved in light-resistant and well-closed bottles